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IJAST

Sustainable and Efficient Wastewater Treatment: A Novel Alginate Bead Membrane Solution

© 2025 by IJAST

Volume 3 Issue 2

Year of Publication : 2025

Author : Chinenyenwa Nkeiruka Nweke, Sunday Uzochukwu John

: 10.56472/25839233/IJAST-V3I2P103

Citation :

Chinenyenwa Nkeiruka Nweke, Sunday Uzochukwu John, 2025. "Sustainable and Efficient Wastewater Treatment: A Novel Alginate Bead Membrane Solution" ESP International Journal of Advancements in Science & Technology (ESP-IJAST)  Volume 3, Issue 2: 12-26.

Abstract :

Alginate, a natural biopolymer, has gained significant attention as a versatile material for developing sustainable and efficient membranes for wastewater treatment. This paper explores the recent advancements in fabricating and optimizing alginate membranes for enhanced performance. Various techniques, including casting, electrospinning, and 3D printing, are discussed for creating alginate membranes with tailored properties. To further optimize the performance of alginate membranes, strategies such as crosslinking, incorporation of porogens, and surface functionalization are employed. These modifications aim to improve mechanical strength, porosity, selectivity, and antifouling properties. Response Surface Methodology (RSM) has emerged as a powerful tool for optimizing the fabrication process, enabling the identification of optimal conditions for specific applications. The integration of alginate membranes with biological treatment processes, such as phycoremediation and mycoremediation, holds great promise for sustainable wastewater treatment. By immobilizing microorganisms on alginate membranes, enhanced biodegradation and pollutant removal can be achieved. Overall, this study provides a comprehensive overview of the state-of-the-art in alginate membrane technology for wastewater treatment. It highlights the potential of alginate membranes as a sustainable and effective solution for addressing global water pollution challenges.

References :

[1] Rafiee F. Alginate: Wastewater treatment. In I. A. Severo, A. B. Mariano, and J. V. C. Vargas (Eds.), Alginate: Applications and Future Perspectives. IntechOpen. (2023) 359-378.

[2] Łabowska MB, Michalak I, and Detyna J. Methods of Extraction, Physicochemical Properties of Alginates and their Applications in Biomedical field – A review. Open Chemistry. 17(1) (2019) 77 - 91.

[3] Shende AD, and Pophali GR. Anaerobic treatment of slaughterhouse wastewater: A review. Environmental Science and Pollution Research. 28(1) (2021) 35 - 55.

[4] Severo IA, Mariano AB, Vargas JVC. Coagulation performance evaluation of alginate as a natural coagulant. Water Practice and Technology. 17(1) (2023) 395 - 408.

[5] Sutirman ZA, Sanagi MM, and Wan Aini WI. Alginate-based adsorbents for removal of metal ions and radionuclides from aqueous solutions: A review. International journal of biological macromolecules. (174) (2021) 216–228.

[6] Md. Mostafizur Rahman, Md. Abdus Shahid, Md. Tanvir Hossain, Md. Sohan Sheikh, Md. Sunjidur Rahman, Nasir Uddin, Abdur Rahim, Ruhul Amin Khan and Imam Hossain. Sources, extractions, and applications of alginate: A review. Discover Applied Sciences. 6(443) (2024). https://doi.org/10.1007/s42452-024-06151-2.

[7] Uysal E, Emil-Kaya E, Yesiltepe-Ozcelik D, and Gurmen S. Nd recovery from wastewater with magnetic calcium alginate ((1,4)-β-D- mannuronic acid and α-L-guluronic acid) hydrogels. ACS Omega. 8(19) (2023) 16762 – 16778.

[8] Phang YN, Chee SY, Lee CO, and Teh YL. Thermal and microbial degradation of alginate-based superabsorbent polymer. Polymer Degradation and Stability. 96(9) (2011) 1653 – 1661.

[9] Qasem NAA, Mohammed RH, and Lawal DU. Author correction: Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water. 4(1) (2021) 52.

[10] Samer M. Biological and Chemical Wastewater Treatment Processes. InTech. 2015. Doi: 10.5772/61250.

[11] Zamani H, Golestani HA, Mousavi SM, Zhiani R, and Hosseini MS. Slaughterhouse wastewater treatment using biological anaerobic and coagulation-flocculation hybrid process. Desalination and Water Treatment. (155) (2019) 64 – 71.

[12] Clementi A., Egger D., Charwat, V., and Kasper C. Cell culture conditions: Cultivation of stem cells under dynamic conditions. Cell Engineering and Regeneration. (2020) 415-447.

[13] Yusoff MS, Azwan AM, Zamri MFMA, and Aziz HA. Removal of colour, turbidity, oil and grease for slaughterhouse Wastewater using electrocoagulation method. AIP Conference Proceedings. (1892) (2017) 040012-1–040012-7.

[14] Crainic R, Drăgan LR, and Fechete R. 1H NMR relaxometry and ATR-FT-IR spectroscopy used for the assessment of wastewater treatment in slaughterhouse. Studia UBB Physica. 63(LXIII) (2018) 49-60.

[15] Fernando W, Lee WW, Han EJ, Ahn G. Alginate-based nanomaterials: Fabrication techniques, properties, and applications. Chemical Engineering Journal. (391) (2020) 123823.

[16] Priyadharshini SD, Babu PS, Manikandan S, Subbaiya R, Govarthanan M, and Karmegam N. Phycoremediation of wastewater for pollutant removal: A green approach to environmental protection and long-term remediation. Environmental Pollution. (290) (2021) 117989.

[17] Huang X., Zhang Y., Yang W., Huang Z., Wang Y. Zhang Z. He Q., Lü, S., Huang Z., Bi X. and Wang X. Effect of traffic restriction on reducing ambient volatile organic compounds (VOCs): Observation-based evaluation during a traffic restriction drill in Guangzhou, China. Atmospheric Environment. (161) (2017) 61 - 70.

[18] Darwish Nawaf Bin, Abdullah Alkhudhiri, Abdulrahman AlAlawi, Hamad AlRomaih, and Nidal Hilal. Experimental investigation of forward osmosis process for boron removal from water, Journal of Water Process Engineering. 38 (101570) (2020) 2214-7144. https://doi.org/10.1016/j.jwpe.2020.101570.

[19] Augustus OO, Kusworo A, and Montoya AI. Review of alginate-based membranes for wastewater treatment. Sustainable Environment Research. (29) (2021) 25.

[20] Liu W, Jiang L, and Wang P. Application of RSM in bioremediation process optimization for heavy metal removal. Journal of Hazardous Materials. (371) (2019) 591 - 598.

[21] Chen C, Li R, Xu Y, Zhang M, Hong H, and Lin H. A novel method integrating response surface method with artificial neural network to optimize membrane fabrication for wastewater treatment. Journal of Cleaner Production. (376) (2022) 134236.

[22] Myers RH. and Montgomery DC. Response Surface Methodology (RSM): Process and Product Optimization Using Designed Experiments. Wiley-Interscience Publication, Hoboken. (2002) 489 - 492.

[23] Javadian H, Ruiz M, and Sastre AM. Response surface methodology based on central composite design for simultaneous adsorption of rare earth elements using nanoporous calcium alginate/carboxymethyl chitosan microbiocomposite powder containing Ni₀.₂Zn₀.₂Fe₂.₆O₄ magnetic nanoparticles: Batch and column studies. International Journal of Biological Macromolecules. (154) (2020) 937 – 953.

[24] Hosseini A, Lee C, and Kim J. Algal bioremediation: Removal of nutrients and contaminants from slaughterhouse wastewater. Bioresource Technology. (323) (2021) 124567.

[25] Abdel-Raouf N, El-Toukhy A, and Gamal GM. A review on the potential uses of alginate encapsulated microalgae for wastewater treatment. Sustainable Energy Technologies and Assessments. (18) (2017) 277 - 285.

[26] Chen W, Chang W, Wang Y. Flow rate impact on algae-based wastewater treatment. Journal of Water Process Engineering. 36 (2020) 101278.

[27] Shahid MU., Najam T., Islam M., Hassan AM., Assiri MA., Rauf A., and Nazir MA. Engineering of metal organic framework (MOF) membrane for waste water treatment: Synthesis, applications and future challenges. Journal of Water Process Engineering. (57) (2024) 104676.

[28] Sun X, Wang C, Su D, Wang G, and Zhong Y. Application of Photocatalytic Materials in Sensors. Adv. Mater. Technol. 5 (2020) 1900993.

[29] Li M, Huang Y, and Xu Z. Packed bed reactors for alginate-immobilized algae in wastewater treatment. Environmental Pollution.(268) (2021) 115840.

[30] Wang L, Zhou Q, and Huang X. Microbial activity enhancement using mushroom substrates for improved wastewater treatment. Journal of Cleaner Production. (353) (2022) 131429.

[31] Zhang X., Ma J., Zheng J., Dai R., Wang X., and Wang, Z. Recent advances in nature-inspired antifouling membranes for water purification. Chemical Engineering Journal. (432) (2022) 134425.

[32] Lee S., Kim T., and Park H. Optimizing bioreactor design for algal-based treatment of industrial wastewater. Environmental Technology. 41(14) (2020) 1771-1783.

[33] Li Z., Zhang X., and Liu W. Comparative study of free and immobilized cells in wastewater treatment. Water Research. (156) (2019) 91–100.

[34] Xuemei J., Zhihua L., Mingsen W., Zhigang Y. and Li J. Response Surface Methodology Approach to Optimize Parameters for Coagulation Process Using Polyaluminum Chloride (PAC). Water. 16(11) (2024) 1470. https://doi.org/10.3390/w16111470.

[35] Onadeji A., Sani SB. and Abubakar UA. Response surface methodology optimization of the effect of pH, contact time, and microbial concentration on chemical oxygen removal potential of vegetable oil industrial effluents. Water Environ Res 96(1) (2024) e10963. Doi 10.1002/wer.1093.

[36] Sudhakar, M. S., Aggarwal, A., and Sah, M. K. Engineering biomaterials for the bioremediation: advances in nanotechnological approaches for heavy metals removal from natural resources. In Emerging technologies in environmental bioremediation. Elsevier. (2020) 323 - 339.

[37] Vijayaraghavan K, and Yun YS. Bacterial biosorbents and biosorption. Biotechnol Adv. 26(3) (2008) 266 - 291. doi:10.1016/j.biotechadv.2008.02.002.

[38] Singh, R. P. and Thakur, I. S. Sustainable wastewater treatment using algal-bacterial consortia: Advances and challenges. Journal of Hazardous Materials. (429) (2023) 128503.

[39] Yu F., Cui T., Yang C., Dai X., and Ma J. κ-Carrageenan/Sodium alginate double-network hydrogel with enhanced mechanical properties, anti-swelling, and adsorption capacity. Chemosphere. (237) (2019) 124417.

[40] Gouda S., and Taha, A. Biosorption of heavy metals as a new alternative method for wastewater treatment: A review. Egyptian Journal of Aquatic Biology and Fisheries. 27(2) (2023) 135 – 153. Doi: 10.21608/EJABF.2023.291671.

Keywords :

Alginate, Membrane, Wastewater, Optimization, Mycoremediation, Phycoremediation.